Synthesis and Characterization of Palladium Supported Amino Functionalized Magnetic-MOF-MIL-101 as an Efficient and Recoverable Catalyst for Mizoroki–Heck Cross-Coupling

Ayat Nuri; Nemanja Vucetic; Jan Henrik Smått; Yaghoub Mansoori; Jyri Pekka Mikkola; Dmitry Yu Murzin

doi:10.1007/s10562-020-03151-w

Synthesis and Characterization of Palladium Supported Amino Functionalized Magnetic-MOF-MIL-101 as an Efficient and Recoverable Catalyst for Mizoroki–Heck Cross-Coupling

Ayat Nuri, Nemanja Vucetic, Jan Henrik Smått, Yaghoub Mansoori, Jyri Pekka Mikkola, Dmitry Yu Murzin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

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Abstract

Magnetic particles were prepared by a hydrothermal method and then successively covered by Metal–Organic-Frameworks MIL-101-NH₂ with a high surface area. This was followed by deposition of Pd(OAc)₂ on Fe₃O₄–NH₂@MIL-101-NH₂ particles. The final catalyst was characterized with FT-IR, nitrogen physisorption, thermogravimetry (TGA), scanning electron microscopy (SEM) combined with energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), vibrating sample magnetometry (VSM), wide-angle X-ray diffraction spectroscopy (XRD) and X-ray photoelectron spectroscopy (XPS). The prepared magnetic catalyst was effectively used in the Heck coupling reaction in the presence of an inorganic base. The reaction parameters such as the base type, amounts of catalyst and solvents, temperature, and substrates ratios were optimized. The catalyst was then magnetically separated, washed, and reused 7 times without losing significantly catalytic activity.

Original language	English
Pages (from-to)	2617-2629
Number of pages	13
Journal	Catalysis Letters
Volume	150
Issue number	9
DOIs	https://doi.org/10.1007/s10562-020-03151-w
Publication status	Published - 1 Sept 2020
MoE publication type	A1 Journal article-refereed

Keywords

FeO–NH@MIL-101-NH
Heck reaction
Magnetic nanoparticles
Metal–organic-frameworks

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title = "Synthesis and Characterization of Palladium Supported Amino Functionalized Magnetic-MOF-MIL-101 as an Efficient and Recoverable Catalyst for Mizoroki–Heck Cross-Coupling",

abstract = " Magnetic particles were prepared by a hydrothermal method and then successively covered by Metal–Organic-Frameworks MIL-101-NH2 with a high surface area. This was followed by deposition of Pd(OAc)2 on Fe3O4–NH2@MIL-101-NH2 particles. The final catalyst was characterized with FT-IR, nitrogen physisorption, thermogravimetry (TGA), scanning electron microscopy (SEM) combined with energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), vibrating sample magnetometry (VSM), wide-angle X-ray diffraction spectroscopy (XRD) and X-ray photoelectron spectroscopy (XPS). The prepared magnetic catalyst was effectively used in the Heck coupling reaction in the presence of an inorganic base. The reaction parameters such as the base type, amounts of catalyst and solvents, temperature, and substrates ratios were optimized. The catalyst was then magnetically separated, washed, and reused 7 times without losing significantly catalytic activity. ",

keywords = "FeO–NH@MIL-101-NH, Heck reaction, Magnetic nanoparticles, Metal–organic-frameworks",

author = "Ayat Nuri and Nemanja Vucetic and Sm{\aa}tt, {Jan Henrik} and Yaghoub Mansoori and Mikkola, {Jyri Pekka} and Murzin, {Dmitry Yu}",

note = "Funding Information: Open access funding provided by Abo Akademi University (ABO). Publisher Copyright: {\textcopyright} 2020, The Author(s). Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",

year = "2020",

month = sep,

day = "1",

doi = "10.1007/s10562-020-03151-w",

language = "English",

volume = "150",

pages = "2617--2629",

journal = "Catalysis Letters",

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number = "9",

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Synthesis and Characterization of Palladium Supported Amino Functionalized Magnetic-MOF-MIL-101 as an Efficient and Recoverable Catalyst for Mizoroki–Heck Cross-Coupling. / Nuri, Ayat; Vucetic, Nemanja ; Smått, Jan Henrik et al.
In: Catalysis Letters, Vol. 150, No. 9, 01.09.2020, p. 2617-2629.

Research output: Contribution to journal › Article › Scientific › peer-review

TY - JOUR

T1 - Synthesis and Characterization of Palladium Supported Amino Functionalized Magnetic-MOF-MIL-101 as an Efficient and Recoverable Catalyst for Mizoroki–Heck Cross-Coupling

AU - Nuri, Ayat

AU - Vucetic, Nemanja

AU - Smått, Jan Henrik

AU - Mansoori, Yaghoub

AU - Mikkola, Jyri Pekka

AU - Murzin, Dmitry Yu

PY - 2020/9/1

Y1 - 2020/9/1

N2 - Magnetic particles were prepared by a hydrothermal method and then successively covered by Metal–Organic-Frameworks MIL-101-NH2 with a high surface area. This was followed by deposition of Pd(OAc)2 on Fe3O4–NH2@MIL-101-NH2 particles. The final catalyst was characterized with FT-IR, nitrogen physisorption, thermogravimetry (TGA), scanning electron microscopy (SEM) combined with energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), vibrating sample magnetometry (VSM), wide-angle X-ray diffraction spectroscopy (XRD) and X-ray photoelectron spectroscopy (XPS). The prepared magnetic catalyst was effectively used in the Heck coupling reaction in the presence of an inorganic base. The reaction parameters such as the base type, amounts of catalyst and solvents, temperature, and substrates ratios were optimized. The catalyst was then magnetically separated, washed, and reused 7 times without losing significantly catalytic activity.

AB - Magnetic particles were prepared by a hydrothermal method and then successively covered by Metal–Organic-Frameworks MIL-101-NH2 with a high surface area. This was followed by deposition of Pd(OAc)2 on Fe3O4–NH2@MIL-101-NH2 particles. The final catalyst was characterized with FT-IR, nitrogen physisorption, thermogravimetry (TGA), scanning electron microscopy (SEM) combined with energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), vibrating sample magnetometry (VSM), wide-angle X-ray diffraction spectroscopy (XRD) and X-ray photoelectron spectroscopy (XPS). The prepared magnetic catalyst was effectively used in the Heck coupling reaction in the presence of an inorganic base. The reaction parameters such as the base type, amounts of catalyst and solvents, temperature, and substrates ratios were optimized. The catalyst was then magnetically separated, washed, and reused 7 times without losing significantly catalytic activity.

KW - FeO–NH@MIL-101-NH

KW - Heck reaction

KW - Magnetic nanoparticles

KW - Metal–organic-frameworks

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DO - 10.1007/s10562-020-03151-w

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VL - 150

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IS - 9

ER -

Synthesis and Characterization of Palladium Supported Amino Functionalized Magnetic-MOF-MIL-101 as an Efficient and Recoverable Catalyst for Mizoroki–Heck Cross-Coupling

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