Adsorption of methylene blue by composite foams containing alkali-activated blast furnace slag and lignin
Bhuyan, M. A. H.; Luukkonen, T. (2023-10-16)
Bhuyan, M. A. H.
Luukkonen, T.
Springer
16.10.2023
Bhuyan, M.A.H., Luukkonen, T. Adsorption of methylene blue by composite foams containing alkali-activated blast furnace slag and lignin. Int. J. Environ. Sci. Technol. 21, 3789–3802 (2024). https://doi.org/10.1007/s13762-023-05245-5
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© The Author(s) 2023. This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
https://creativecommons.org/licenses/by/4.0/
© The Author(s) 2023. This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
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Julkaisun pysyvä osoite on
https://urn.fi/URN:NBN:fi-fe20231024141097
https://urn.fi/URN:NBN:fi-fe20231024141097
Tiivistelmä
Abstract
Adsorption is a promising method to remove dyes, such as methylene blue, from wastewater. In this study, a dynamic adsorption set-up was used to treat synthetic wastewater containing methylene blue by using alkali-activated blast furnace slag and lignin composite foam. The structure of the foam without lignin was first optimized by comparing cationic and non-ionic surfactants in the preparation of the foam via the direct foaming method. The selection of the surfactant affects the porosity and pore structure of the foam through different abilities to stabilize the gas–liquid interface and changes in the viscosity of the fresh-state paste. The foam prepared with non-ionic Triton X-114 surfactant had the highest adsorption performance and was selected for the optimization of adsorption conditions. The optimized conditions were 5 mg/L influent concentration of methylene blue, pH of 7, and flow rate of 1.0 L/h (corresponding to ~ 9 min empty bed contact time). To further enhance the methylene blue adsorption performance, a composite containing lignin was prepared. The optimum lignin amount in the foam was 0.8 wt% and it resulted a ~ 93% higher adsorption amount compared to the foam without lignin. The highest cumulative adsorption capacity in this dynamic adsorption setup was 39.5 mg/g, which is among the highest reported values for methylene blue removal by monolithic adsorbents. The present study provides a proof of concept for the enhancement of adsorption performance of alkali-activated materials by introduction of lignin into the structure.
Adsorption is a promising method to remove dyes, such as methylene blue, from wastewater. In this study, a dynamic adsorption set-up was used to treat synthetic wastewater containing methylene blue by using alkali-activated blast furnace slag and lignin composite foam. The structure of the foam without lignin was first optimized by comparing cationic and non-ionic surfactants in the preparation of the foam via the direct foaming method. The selection of the surfactant affects the porosity and pore structure of the foam through different abilities to stabilize the gas–liquid interface and changes in the viscosity of the fresh-state paste. The foam prepared with non-ionic Triton X-114 surfactant had the highest adsorption performance and was selected for the optimization of adsorption conditions. The optimized conditions were 5 mg/L influent concentration of methylene blue, pH of 7, and flow rate of 1.0 L/h (corresponding to ~ 9 min empty bed contact time). To further enhance the methylene blue adsorption performance, a composite containing lignin was prepared. The optimum lignin amount in the foam was 0.8 wt% and it resulted a ~ 93% higher adsorption amount compared to the foam without lignin. The highest cumulative adsorption capacity in this dynamic adsorption setup was 39.5 mg/g, which is among the highest reported values for methylene blue removal by monolithic adsorbents. The present study provides a proof of concept for the enhancement of adsorption performance of alkali-activated materials by introduction of lignin into the structure.
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