Radiological and leaching assessment of an ettringite-based mortar from ladle slag and phosphogypsum
Gijbels, Katrijn; Nguyen, Hoang; Kinnunen, Päivö; Samyn, Pieter; Schroeyers, Wouter; Pontikes, Yiannis; Schreurs, Sonja; Illikainen, Mirja (2019-12-03)
Katrijn Gijbels, Hoang Nguyen, Paivo Kinnunen, Pieter Samyn, Wouter Schroeyers, Yiannis Pontikes, Sonja Schreurs, Mirja Illikainen, Radiological and leaching assessment of an ettringite-based mortar from ladle slag and phosphogypsum, Cement and Concrete Research, Volume 128, 2020, 105954, ISSN 0008-8846, https://doi.org/10.1016/j.cemconres.2019.105954
© 2019. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/.
https://creativecommons.org/licenses/by-nc-nd/4.0/
https://urn.fi/URN:NBN:fi-fe2019120545874
Tiivistelmä
Abstract
In this investigation, ettringite-based mortars were synthesized from ladle slag (LS) and phosphogypsum (PG), promoting the concept of a circular economy. However, the reuse of naturally occurring radioactive materials (NORM), such as PG, requires radiological investigation. Also, the immobilization degree for contaminants contained in PG should be evaluated. The former was investigated using gamma spectroscopy and radon exhalation/emanation tests, while the latter was assessed using an up-flow percolation column test according to the CEN/TS 16637‐3. The produced mortars comply with current legislation on naturally occurring radionuclides (NOR) in building materials, proving that they can be safely used for building purposes. The radon emanation decreased upon increasing the Polish PG content, which was mainly determined by the microporosity. The specific surface areas were 20‐30 times lower than conventional cement, and the immobilization degree for contaminants was generally high (>90%). This investigation demonstrates high potential for PG reuse in ettringite-based mortars.
Kokoelmat
- Avoin saatavuus [32009]